Hello,
Nicolas gave you the process to follow
You'll have to loop on the array $cart->products and sum the price_value - price_value_without_discount of each product to be able to get the total amount of discount so that you can just echo it at the correct place, between the sub total and the total blocks of code.
The explanation have details and can be easily translated to PHP code if you have the basis knowledge.
Afterwards, I'm afraid that it's going outside the limit of our support ; like Nicolas mentioned, it is related to customization.
Regards,