Hi,
The Merchant name is the name you want your customers to see for your shop on PayPal. So usually you want to enter the name of your shop.
The issue you're reporting indicates that amount paid by the customer is different from the total amount of the order in HikaShop.
This can happen if you have the "round prices during calculations" setting turned off in the HikaShop configuration, because in that case HikaShop and PayPal won't calculate the total amount in the same way.
So please check this.