Hi,
Sorry but there is no attached file.
To add other recipients to the email, you can edit the html part of this one via the menu System > Emails and then add the following code at the end:
<?php
$mailer = JFactory::getMailer();
$recipients = array('myfirst@recipient.com','mysecond@recipient.com');
$mailer->addRecipients($recipients);
?>
Regarding the "Dirección de desvío" and "Dirección de desvío para los avisos de pago" I am not sure about what it is, could you give us the english words of that ? I guess that it's order number and invoice number but I am not sure.
If it is, it is an option which allow you to edit the format of the order number and the invoice number.