You can edit the file 'invoice' under 'order' in Display > Views for that. It's not possible that you don't have it or you wouldn't be able to display invoices
The CSS is inlined in there so you can directly edit it there.
If you want to remove the payment fee line, you can remove the code
<tr>
<td colspan="2">
</td>
<td class="key">
<label>
<?php echo JText::_( 'HIKASHOP_PAYMENT' ); ?>
</label>
</td>
<td>
<?php echo $this->currencyHelper->format($this->order->order_payment_price,$this->order->order_currency_id); ?>
</td>
</tr>
The PDF plugin has to use another layout in order to render properly in the PDF. So it doesn't convert it.