Hi,
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There is no PDF catalog generation plugin per se, but you can have something pretty close :
You can use the Products listing menu item that HikaShop creates by default to have a listing of all the products of the store (increase the number of elements option of the menu so that you have them all on one page). Then, you can access it on your frontend, add the parameter ?tmpl=component to the URL to remove the template and the modules around and then click on the print button of your browser to print it. Then, if you have a virtual PDF printer installed on your computer, you can use it to generate the PDF out of that listing.
If you want to generate that automatically and periodically, I'm sure that you could find some tool out there which could automatically convert a HTML page into a PDF. For example, that tool with a cron task:
www.verypdf.com/app/html-converter/html-converter-cmd.html